Before saving Click the EYE icon next to the background layer tom turn of its visibility.
Then use the optimiser as this gives a preview Of what you are going to end up with.
File Export Png optimiser ( I have added the Gif, Jpeg and Png Icons to my Main toolbar as I use them a LOT)
On the transparency tab in the optimiser set "Alpha Channel Transparency"
For what area of the image you would like to be transparent set "Existing image or layer transparency"
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