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PSP is a bitmap editing application and Xtreme is a vector drawing application.
If you can save your file from PSP as a PNG with alpha channel transparency or Photoshop or TIFF with alpha channel transparency then you will not have the white background.
Basically when you save a file in PSP you are creating a rectangular bitmap. If the bitmap was not created on a transparency layer it will have a background which will be the same color as your page.
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