We've had a little discussion on our forum concerning, "What headline font goes with which body copy typeface?", and although we can make recommendations, it might be more fun for you to learn about typographic compatibilities in the form of an online game, like Type Connection.
This is good, interactive stuff, for discovering what san serifs go with serif fonts, about font weights and other educational stuff that might make you a better designer!
My Best,
Gary
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