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Sorry Frank, as I don't have Total Commander, I cannot really dig into it any further.

Acorn

Frank, a quick guess is you need it to be:
file:///C:\program%20files\Wincmd\TOTALCMD64.EXE%20(/O%20/R="file:///e:\Box%20Sync\TotCmd")

Some info here:...

GK5, Just replace file:///"c:\StandAlone Apps\Autoruns V13.51\Autoruns.exe" with file:///c:\StandAlone%20Apps\Autoruns%20V13.51\Autoruns.exe or...

Frank, perfectly possible.

The simplest approach is a quick demo.

I have Portable Apps on my I:\ Drive.
The Shortcut is I:\PortableApps\Start.exe.
You would create a Link in Xara to...